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Transition-metal-free radical approach for the synthesis of isothiocyanates by pyridinium 1,4-zwitterionic thiolates as a sulfur source

Herein, we disclose a novel, mild, transition-metal-free approach to synthesizing diversely functionalized isothiocyanates from the corresponding isocyanide precursors, achieving high to excellent yields (up to 97%). The current method sheds light on the reactivity of pyridinium 1,4-zwitterionic thi...

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Hauptverfasser: Mobarakeh, Fatemeh Abdiyan (VerfasserIn) , Khosravi, Hormoz (VerfasserIn) , Akbari, Alireza (VerfasserIn) , Rominger, Frank (VerfasserIn) , Balalaie, Saeed (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: January 28, 2025
In: The journal of organic chemistry
Year: 2025, Jahrgang: 90, Heft: 5, Pages: 1912-1921
ISSN:1520-6904
DOI:10.1021/acs.joc.4c02593
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1021/acs.joc.4c02593
Verlag, kostenfrei, Volltext: https://pubs.acs.org/doi/10.1021/acs.joc.4c02593
Volltext
Verfasserangaben:Fatemeh Abdiyan Mobarakeh, Hormoz Khosravi, Alireza Akbari, Frank Rominger, and Saeed Balalaie

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