Grazing-incidence small-angle neutron scattering at high pressure (HP-GISANS): a soft matter feasibility study on grafted brush films
Grazing-incidence small-angle neutron scattering (GISANS) under pressure (HP-GISANS) at the solid (Si)-liquid (D2O) interface is demonstrated for the pressure-induced lateral morphological characterization of the nanostructure in thin (<100 nm) soft matter films. We demonstrate feasibility by inv...
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| Main Authors: | , , , , , , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
4 November 2024
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| In: |
Journal of applied crystallography
Year: 2024, Volume: 57, Issue: 6, Pages: 1978-1983 |
| ISSN: | 1600-5767 |
| DOI: | 10.1107/S1600576724009130 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1107/S1600576724009130 Verlag, lizenzpflichtig, Volltext: https://journals.iucr.org/j/issues/2024/06/00/xx5058/ |
| Author Notes: | A. Vagias, T. Manouras, A. Buchner, P. Gutfreund, L. Porcar, M. Jacques, L. Chiappisi, D.P. Kosbahn, M. Wolf, L. Guasco, R. Dahint, M. Vamvakaki, P. Müller-Buschbaum |
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| 520 | |a Grazing-incidence small-angle neutron scattering (GISANS) under pressure (HP-GISANS) at the solid (Si)-liquid (D2O) interface is demonstrated for the pressure-induced lateral morphological characterization of the nanostructure in thin (<100 nm) soft matter films. We demonstrate feasibility by investigating a hydrophobic {poly[(2,2,3,3,4,4,5,5-octafluoro)pentyl methacrylate]} (POFPMA)-hydrophilic {poly[2-(dimethylamino)ethyl methacrylate]} (PDMAEMA) brush mixture of strong incompatibility between the homopolymers, anchored on Si, at T = 45°C for two pressures, P = 1 bar and P = 800 bar. Our GISANS results reveal nanostructural rearrangements with increasing P, underlining P-induced effects in tethered polymer brush layers swollen with bulk solvent. | ||
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| 700 | 1 | |a Porcar, L. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Jacques, M. |e VerfasserIn |4 aut | |
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