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Steering magnetic coupling in diradical nonbenzenoid nanographenes

Magnetic properties arising from controlled spin-spin interactions hold great promise for applications in spintronics and quantum technologies. In nanographenes, pentagonal and heptagonal rings introduce geometric frustration and sublattice imbalance, fundamentally altering spin localization and fac...

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Main Authors: Liu, Ye (Author) , Weigold, Svenja (Author) , Yan, Linghao (Author) , Wei, Zixuan (Author) , Hanne, Malte (Author) , Tverskoy, Olena (Author) , You, Sifan (Author) , Xie, Miao (Author) , Zhang, Yanfang (Author) , Chen, Qiang (Author) , Rominger, Frank (Author) , Bunz, Uwe H. F. (Author) , Freudenberg, Jan (Author) , Du, Shixuan (Author) , Müllen, Klaus (Author) , Chi, Lifeng (Author)
Format: Article (Journal)
Language:English
Published: 2 July 2025
In: Journal of the American Chemical Society
Year: 2025, Volume: 147, Issue: 26, Pages: 23103-23112
ISSN:1520-5126
DOI:10.1021/jacs.5c06416
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.5c06416
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Author Notes:Ye Liu, Svenja Weigold, Linghao Yan, Zixuan Wei, Malte Hanne, Olena Tverskoy, Sifan You, Miao Xie, Yanfang Zhang, Qiang Chen, Frank Rominger, Uwe H.F. Bunz, Jan Freudenberg, Shixuan Du, Klaus Müllen, and Lifeng Chi
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Summary:Magnetic properties arising from controlled spin-spin interactions hold great promise for applications in spintronics and quantum technologies. In nanographenes, pentagonal and heptagonal rings introduce geometric frustration and sublattice imbalance, fundamentally altering spin localization and facilitating the emergence of open-shell structures. The precise engineering of magnetic order and coupling strength in the resulting nonbenzenoid nanographenes, however, remains a challenging and underexplored area. Here, we demonstrate an on-surface synthesis of nanographenes incorporating five- and seven-membered rings through a sequence of intramolecular C-C bond formations between methyl and aryl units. Two products are generated: the partially cyclized intermediate MAAT and the fully cyclized end product MAZC. Due to the presence of iodo groups, the resulting monomers obtained can be covalently connected via Ullmann-like coupling in variable modes, enabling programmable spin arrangements. While MAZC exists as a nonmagnetic species, MAAT featuring one seven-membered ring holds an unpaired S = 1/2 spin and exhibits Kondo resonance on a metal surface. By change of the connectivity between two MAAT units, tunable magnetic ground states and precise control over the exchange-interaction strength can be achieved. These findings, supported by scanning probe microscopy and density functional theory, establish a novel strategy for designing defined carbon nanostructures with tailored topological defects and offer fine-tuned manipulation of molecular magnetism.
Item Description:Online veröffentlicht: 16. Juni 2025
Gesehen am 22.10.2025
Physical Description:Online Resource
ISSN:1520-5126
DOI:10.1021/jacs.5c06416

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