Targeted synthesis of a positional isomer of aromatic N-methyl N-confused corrole and its organocopper(III) complex
We report the synthesis, spectroscopic analyses and solid-state structural evidence of an unprecedented positional isomer of aromatic [18] N-confused corrole exhibiting vis-NIR absorption. Copper metalation led to an organo-copper(III) complex with preserved aromaticity.
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
18 November 2025
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| In: |
Chemical communications
Year: 2025, Jahrgang: 61, Heft: 89, Pages: 17436-17439 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D5CC05372B |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D5CC05372B Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc05372b 
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| Verfasserangaben: | Anirban Panua, Gunasekaran Velmurugan, Peter Comba and Harapriya Rath |
| Zusammenfassung: | We report the synthesis, spectroscopic analyses and solid-state structural evidence of an unprecedented positional isomer of aromatic [18] N-confused corrole exhibiting vis-NIR absorption. Copper metalation led to an organo-copper(III) complex with preserved aromaticity. |
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| Beschreibung: | Erstveröffentlichung: 6. Oktober 2025 Gesehen am 02.02.2026 |
| Beschreibung: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/D5CC05372B |