Synthesis of enantiopure (3)cyclorubicenes
The interest in chiral nanohoops and nanotubes as well as their chiroptical properties has steadily increased in recent years. The synthesis of pentagon containing enantiopure [3]cyclorubicenes, which are cutouts and potential precursors of chiral Haeckelite nanotubes is presented, based on enantiop...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2 January 2026
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| In: |
Angewandte Chemie. International edition
Year: 2026, Volume: 65, Issue: 1, Pages: 1-10 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202520880 |
| Online Access: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202520880 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202520880 
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| Author Notes: | Moritz P. Schuldt, Frank Rominger, and Michael Mastalerz |
| Summary: | The interest in chiral nanohoops and nanotubes as well as their chiroptical properties has steadily increased in recent years. The synthesis of pentagon containing enantiopure [3]cyclorubicenes, which are cutouts and potential precursors of chiral Haeckelite nanotubes is presented, based on enantiopure “corner units”. The resulting enantiopure nanohoops were studied for their electronic and chiroptical properties with one of the highest dissymmetry values reported for CPPs of up to 2.3 × 10−2. |
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| Item Description: | Im Titel erscheint die 3 in eckigen Klammern Online verfügbar: 10. November 2025 Gesehen am 11.02.2026 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202520880 |