Expanding the scope of the gold(I)-catalyzed Rautenstrauch rearrangement: protic additives
The synthesis of substituted 2-cyclopentenones using a commercially available gold(I) catalyst is described under flexible reaction conditions. During the course of our investigations, we discovered that using a proton source as an additive is required to obtain the desired substituted cyclopentenon...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
September 23, 2016
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| In: |
Organic letters
Year: 2016, Volume: 18, Issue: 19, Pages: 5058-5061 |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/acs.orglett.6b02505 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1021/acs.orglett.6b02505
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| Author Notes: | Cédric Bürki, Andrew Whyte, Sebastian Arndt, A. Stephen K. Hashmi, Mark Lautens |
| Summary: | The synthesis of substituted 2-cyclopentenones using a commercially available gold(I) catalyst is described under flexible reaction conditions. During the course of our investigations, we discovered that using a proton source as an additive is required to obtain the desired substituted cyclopentenones in good yields. |
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| Item Description: | Gesehen am 25.08.2017 |
| Physical Description: | Online Resource |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/acs.orglett.6b02505 |