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Expanding the scope of the gold(I)-catalyzed Rautenstrauch rearrangement: protic additives

The synthesis of substituted 2-cyclopentenones using a commercially available gold(I) catalyst is described under flexible reaction conditions. During the course of our investigations, we discovered that using a proton source as an additive is required to obtain the desired substituted cyclopentenon...

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Bibliographische Detailangaben
Hauptverfasser: Bürki, Cédric (Verfasst von) , Arndt, Sebastian (Verfasst von) , Hashmi, A. Stephen K. (Verfasst von)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: September 23, 2016
In: Organic letters
Year: 2016, Jahrgang: 18, Heft: 19, Pages: 5058-5061
ISSN:1523-7052
DOI:10.1021/acs.orglett.6b02505
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1021/acs.orglett.6b02505
Volltext
Verfasserangaben:Cédric Bürki, Andrew Whyte, Sebastian Arndt, A. Stephen K. Hashmi, Mark Lautens
Beschreibung
Zusammenfassung:The synthesis of substituted 2-cyclopentenones using a commercially available gold(I) catalyst is described under flexible reaction conditions. During the course of our investigations, we discovered that using a proton source as an additive is required to obtain the desired substituted cyclopentenones in good yields.
Beschreibung:Gesehen am 25.08.2017
Beschreibung:Online Resource
ISSN:1523-7052
DOI:10.1021/acs.orglett.6b02505

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