Expanding the scope of the gold(I)-catalyzed Rautenstrauch rearrangement: protic additives

The synthesis of substituted 2-cyclopentenones using a commercially available gold(I) catalyst is described under flexible reaction conditions. During the course of our investigations, we discovered that using a proton source as an additive is required to obtain the desired substituted cyclopentenon...

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Bibliographic Details
Main Authors: Bürki, Cédric (Author) , Arndt, Sebastian (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: September 23, 2016
In: Organic letters
Year: 2016, Volume: 18, Issue: 19, Pages: 5058-5061
ISSN:1523-7052
DOI:10.1021/acs.orglett.6b02505
Online Access:Verlag, Volltext: http://dx.doi.org/10.1021/acs.orglett.6b02505
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Author Notes:Cédric Bürki, Andrew Whyte, Sebastian Arndt, A. Stephen K. Hashmi, Mark Lautens

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