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Gold(I) vinylidene complexes as reactive intermediates and their tendency to π-backbond

We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

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Bibliographic Details
Main Authors: Nunes dos Santos Comprido, Laura (Author) , Klein, Johannes E. M. N. (Author) , Knizia, Gerald (Author) , Kästner, Johannes (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 28 January 2016
In: Chemistry - a European journal
Year: 2016, Volume: 22, Issue: 9, Pages: 2892-2895
ISSN:1521-3765
DOI:10.1002/chem.201504511
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/chem.201504511
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.201504511/abstract
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Author Notes:Laura Nunes dos Santos Comprido, Johannes E.M.N. Klein, Gerald Knizia, Johannes Kästner, and A. Stephen K. Hashmi
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Summary:We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
Item Description:Gesehen am 29.09.2017
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201504511

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