Gold(I) vinylidene complexes as reactive intermediates and their tendency to π-backbond
We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
28 January 2016
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| In: |
Chemistry - a European journal
Year: 2016, Jahrgang: 22, Heft: 9, Pages: 2892-2895 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201504511 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/chem.201504511 Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.201504511/abstract 
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| Verfasserangaben: | Laura Nunes dos Santos Comprido, Johannes E.M.N. Klein, Gerald Knizia, Johannes Kästner, and A. Stephen K. Hashmi |
| Zusammenfassung: | We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates. |
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| Beschreibung: | Gesehen am 29.09.2017 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201504511 |