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Gold(I) vinylidene complexes as reactive intermediates and their tendency to π-backbond

We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

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Bibliographische Detailangaben
Hauptverfasser: Nunes dos Santos Comprido, Laura (VerfasserIn) , Klein, Johannes E. M. N. (VerfasserIn) , Knizia, Gerald (VerfasserIn) , Kästner, Johannes (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 28 January 2016
In: Chemistry - a European journal
Year: 2016, Jahrgang: 22, Heft: 9, Pages: 2892-2895
ISSN:1521-3765
DOI:10.1002/chem.201504511
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1002/chem.201504511
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.201504511/abstract
Volltext
Verfasserangaben:Laura Nunes dos Santos Comprido, Johannes E.M.N. Klein, Gerald Knizia, Johannes Kästner, and A. Stephen K. Hashmi

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