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Facile synthesis of functionalized carbene metal complexes from coordinated isonitriles

The scope and limitations of the isonitrile-based NHC template synthesis were investigated with a series of precursors containing a nucleophilic amine in combination with tethered electrophiles. In the case of alkynes and phosphonic esters as electrophiles no ring closure was observed and new functi...

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Bibliographic Details
Main Authors: Lothschütz, Christian (Author) , Wurm, Thomas (Author) , Zeiler, Anna (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 4 February 2016
In: Chemistry
Year: 2016, Volume: 11, Issue: 3, Pages: 342-346
ISSN:1861-471X
DOI:10.1002/asia.201500353
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/asia.201500353
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/asia.201500353/abstract
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Author Notes:Christian Lothschütz, Thomas Wurm, Anna Zeiler, Alexander Freiherr v. Falkenhausen, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
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Summary:The scope and limitations of the isonitrile-based NHC template synthesis were investigated with a series of precursors containing a nucleophilic amine in combination with tethered electrophiles. In the case of alkynes and phosphonic esters as electrophiles no ring closure was observed and new functionalized NAC gold complexes were obtained. By the use of unsaturated esters and phosphonic esters as Michael acceptors in the amine precursors, ester-modified gold and palladium NHC complexes were accessible in high efficiency.
Item Description:Gesehen am 02.10.2017
Jahr auch angegeben als: First published 3 July 2015
Physical Description:Online Resource
ISSN:1861-471X
DOI:10.1002/asia.201500353

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