Pyrrolizidine alkaloids from Onosma arenaria (Boraginaceae)

Uplandicine, a 1,2-unsaturated pyrrolizidine alkaloid esterified with acetyl and echimidinyl moieties at C-7 and C-9, respectively, was isolated as a major component from the alkaloid extract of Onosma arenaria. Its structure was confirmed by MS (EI and positive FAB), 1H- and 13C-NMR analysis. Furth...

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Bibliographic Details
Main Authors: El-Shazly, Assem (Author) , Abdel-Ghani, Afaf (Author) , Wink, Michael (Author)
Format: Article (Journal)
Language:English
Published: 2003
In: Biochemical systematics and ecology
Year: 2003, Volume: 31, Issue: 5, Pages: 477-485
ISSN:1873-2925
DOI:10.1016/S0305-1978(02)00177-1
Online Access:Verlag, Volltext: http://dx.doi.org/10.1016/S0305-1978(02)00177-1
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Author Notes:Assem El-Shazly, Afaf Abdel-Ghani, Michael Wink
Description
Summary:Uplandicine, a 1,2-unsaturated pyrrolizidine alkaloid esterified with acetyl and echimidinyl moieties at C-7 and C-9, respectively, was isolated as a major component from the alkaloid extract of Onosma arenaria. Its structure was confirmed by MS (EI and positive FAB), 1H- and 13C-NMR analysis. Furthermore, nine minor alkaloids were identified on the basis of mass spectral data and/or Kovats retention indices.
Item Description:Gesehen am 04.10.2017
Physical Description:Online Resource
ISSN:1873-2925
DOI:10.1016/S0305-1978(02)00177-1