Strong distortions in hexacarbonyldicobalt complexes by push-pull effects

Push-pull substituted alkynes with a thioether moiety in the α position and a sulfoxide or a sulfone moiety in the α′ position are reacted with octacarbonyldicobalt to create highly distorted hexacarbonyldicobalt complexes.

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Bibliographic Details
Main Authors: Werz, Daniel B. (Author) , Bleiholder, Christian (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 26 May 2006
In: Journal of organometallic chemistry
Year: 2006, Volume: 691, Issue: 18, Pages: 3943-3947
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2006.05.016
Online Access:Verlag, Volltext: http://dx.doi.org/10.1016/j.jorganchem.2006.05.016
Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X0600369X
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Author Notes:Daniel B. Werz, Christian Bleiholder, Rolf Gleiter, Frank Rominger
Description
Summary:Push-pull substituted alkynes with a thioether moiety in the α position and a sulfoxide or a sulfone moiety in the α′ position are reacted with octacarbonyldicobalt to create highly distorted hexacarbonyldicobalt complexes.
Item Description:Gesehen am 09.10.2017
Physical Description:Online Resource
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2006.05.016