Direct observation of t 2g orbital ordering in magnetite
Using soft-x-ray diffraction at the site-specific resonances in the Fe L2,3 edge, we find clear evidence for orbital and charge ordering in magnetite below the Verwey transition. The spectra show directly that the (0012) diffraction peak (in cubic notation) is caused by t2g orbital ordering at octah...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
17 January 2008
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| In: |
Physical review letters
Year: 2008, Volume: 100, Issue: 2 |
| ISSN: | 1079-7114 |
| DOI: | 10.1103/PhysRevLett.100.026406 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1103/PhysRevLett.100.026406 Verlag, Volltext: https://link.aps.org/doi/10.1103/PhysRevLett.100.026406 |
| Author Notes: | J. Schlappa, C. Schüßler-Langeheine, C.F. Chang, H. Ott, A. Tanaka, Z. Hu, M.W. Haverkort, E. Schierle, E. Weschke, G. Kaindl, and L.H. Tjeng |
| Summary: | Using soft-x-ray diffraction at the site-specific resonances in the Fe L2,3 edge, we find clear evidence for orbital and charge ordering in magnetite below the Verwey transition. The spectra show directly that the (0012) diffraction peak (in cubic notation) is caused by t2g orbital ordering at octahedral Fe2+ sites and the (001) by a spatial modulation of the t2g occupation. |
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| Item Description: | Der Buchstabe "t" im Titel ist kursiv und Gruppe "2g" ist tiefgestellt Gesehen am 07.11.2017 |
| Physical Description: | Online Resource |
| ISSN: | 1079-7114 |
| DOI: | 10.1103/PhysRevLett.100.026406 |