Local electronic structure and magnetic properties of LaMn0.5Co0.5O3 studied by x-ray absorption and magnetic circular dichroism spectroscopy
We have studied the local electronic structure of LaMn0.5Co0.5O3 using soft-x-ray absorption spectroscopy at the Co-L_3,2 and Mn-L_3,2 edges. We found a high-spin Co^{2+}--Mn^{4+} valence state for samples with the optimal Curie temperature. We discovered that samples with lower Curie temperatures c...
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| Main Authors: | , |
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| Format: | Article (Journal) Chapter/Article |
| Language: | English |
| Published: |
2008
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| In: |
Arxiv
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| Online Access: | Verlag, kostenfrei, Volltext: http://arxiv.org/abs/0709.3243
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| Author Notes: | T. Burnus, Z. Hu, H. H. Hsieh, V. L. J. Joly, P. A. Joy, M. W. Haverkort, Hua Wu, A. Tanaka, H.-J. Lin, C. T. Chen, L. H. Tjeng |
| Summary: | We have studied the local electronic structure of LaMn0.5Co0.5O3 using soft-x-ray absorption spectroscopy at the Co-L_3,2 and Mn-L_3,2 edges. We found a high-spin Co^{2+}--Mn^{4+} valence state for samples with the optimal Curie temperature. We discovered that samples with lower Curie temperatures contain low-spin nonmagnetic Co^{3+} ions. Using soft-x-ray magnetic circular dichroism we established that the Co^{2+} and Mn^{4+} ions are ferromagnetically aligned. We revealed also that the Co^{2+} ions have a large orbital moment: m_orb/m_spin ~ 0.47. Together with model calculations, this suggests the presence of a large magnetocrystalline anisotropy in the material and predicts a non-trivial temperature dependence for the magnetic susceptibility. |
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| Item Description: | Die Gruppen "0.5" und die Ziffer "3" im Titel sind tiefgestellt Gesehen am 27.11.2017 |
| Physical Description: | Online Resource |