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How boron doping shapes the optoelectronic properties of canonical and phenylene-containing oligoacenes: a combined experimental and theoretical investigation

Optimized syntheses of 6,13-dimesityl-6,13-dihydro-6,13-diborapentacene (DBP) and a related compound (DBI) featuring two biphenylene-2,3-diyl units in place of naphthalene-2,3-diyl moieties are reported. Striking differences between the optoelectronic properties of DBP and DBI have been experimental...

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Bibliographic Details
Main Authors: Kirschner, Sven (Author) , Mewes, Jan-Michael (Author) , Dreuw, Andreas (Author)
Format: Article (Journal)
Language:English
Published: 27 March 2017
In: Chemistry - a European journal
Year: 2017, Volume: 23, Issue: 21, Pages: 5104-5116
ISSN:1521-3765
DOI:10.1002/chem.201700056
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/chem.201700056
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.201700056/abstract
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Author Notes:Sven Kirschner, Jan-Michael Mewes, Michael Bolte, Hans-Wolfram Lerner, Andreas Dreuw, and Matthias Wagner
Description
Summary:Optimized syntheses of 6,13-dimesityl-6,13-dihydro-6,13-diborapentacene (DBP) and a related compound (DBI) featuring two biphenylene-2,3-diyl units in place of naphthalene-2,3-diyl moieties are reported. Striking differences between the optoelectronic properties of DBP and DBI have been experimentally observed, and explained by quantum chemical calculations.
Item Description:Gesehen am 01.12.2017
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201700056

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