Gold-based frustrated Lewis acid/base pairs (FLPs)
The principle of frustrated Lewis acid/base pairs has reached gold chemistry. Based on sterical repulsion at the gold center, an otherwise typical coordination can be prevented, which induces new reactivity patterns. This review explains the basic principles and the development of this type of chemi...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
13 September 2017
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| In: |
Gold bulletin
Year: 2017, Volume: 50, Issue: 3, Pages: 267-282 |
| ISSN: | 2190-7579 |
| DOI: | 10.1007/s13404-017-0219-7 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1007/s13404-017-0219-7 Verlag, Volltext: https://link.springer.com/article/10.1007/s13404-017-0219-7 
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| Author Notes: | Sebastian Arndt, Matthias Rudolph, A. Stephen K. Hashmi |
| Summary: | The principle of frustrated Lewis acid/base pairs has reached gold chemistry. Based on sterical repulsion at the gold center, an otherwise typical coordination can be prevented, which induces new reactivity patterns. This review explains the basic principles and the development of this type of chemistry, and then summarizes the latest developments in this quickly-moving field. In addition, the future perspectives for combining stoichiometric gold chemistry and gold catalysis with FLP chemistry are discussed. |
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| Item Description: | Gesehen am 04.12.2017 |
| Physical Description: | Online Resource |
| ISSN: | 2190-7579 |
| DOI: | 10.1007/s13404-017-0219-7 |