The conformational stability of gaseous 1-butene studied by femtosecond nonlinear spectroscopy and ab initio calculations
1-Butene was investigated by rotational femtosecond degenerate four-wave mixing spectroscopy (fs DFWM) under supersonic expansion conditions as well as by quantum chemical calculations. Fs DFWM is a time-resolved rotational Raman spectroscopy, which allows for precise determination of rotational con...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
12 May 2011
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| In: |
Vibrational spectroscopy
Year: 2011, Volume: 56, Issue: 1, Pages: 13-18 |
| ISSN: | 0924-2031 |
| DOI: | 10.1016/j.vibspec.2010.07.006 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1016/j.vibspec.2010.07.006 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S092420311000113X 
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| Author Notes: | Maksim Kunitski, Stefan Knippenberg, Andreas Dreuw, Bernhard Brutschy |
| Summary: | 1-Butene was investigated by rotational femtosecond degenerate four-wave mixing spectroscopy (fs DFWM) under supersonic expansion conditions as well as by quantum chemical calculations. Fs DFWM is a time-resolved rotational Raman spectroscopy, which allows for precise determination of rotational constants. The experimental fs DFWM spectrum was successfully reproduced by a fitted simulation using a single structure ascribed to the gauche conformer of 1-butene. |
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| Item Description: | Gesehen am 18.12.2017 Available online 3 August 2010 |
| Physical Description: | Online Resource |
| ISSN: | 0924-2031 |
| DOI: | 10.1016/j.vibspec.2010.07.006 |