The conformational stability of gaseous 1-butene studied by femtosecond nonlinear spectroscopy and ab initio calculations
1-Butene was investigated by rotational femtosecond degenerate four-wave mixing spectroscopy (fs DFWM) under supersonic expansion conditions as well as by quantum chemical calculations. Fs DFWM is a time-resolved rotational Raman spectroscopy, which allows for precise determination of rotational con...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
12 May 2011
|
| In: |
Vibrational spectroscopy
Year: 2011, Jahrgang: 56, Heft: 1, Pages: 13-18 |
| ISSN: | 0924-2031 |
| DOI: | 10.1016/j.vibspec.2010.07.006 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1016/j.vibspec.2010.07.006 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S092420311000113X 
|
| Verfasserangaben: | Maksim Kunitski, Stefan Knippenberg, Andreas Dreuw, Bernhard Brutschy |
| Zusammenfassung: | 1-Butene was investigated by rotational femtosecond degenerate four-wave mixing spectroscopy (fs DFWM) under supersonic expansion conditions as well as by quantum chemical calculations. Fs DFWM is a time-resolved rotational Raman spectroscopy, which allows for precise determination of rotational constants. The experimental fs DFWM spectrum was successfully reproduced by a fitted simulation using a single structure ascribed to the gauche conformer of 1-butene. |
|---|---|
| Beschreibung: | Gesehen am 18.12.2017 Available online 3 August 2010 |
| Beschreibung: | Online Resource |
| ISSN: | 0924-2031 |
| DOI: | 10.1016/j.vibspec.2010.07.006 |