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New chromium(III) complexes as highly active catalysts for olefin polymerization

Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5-8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly...

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Bibliographic Details
Main Authors: Enders, Markus (Author) , Fernández, Pablo (Author) , Ludwig, Gunter (Author) , Pritzkow, Hans (Author)
Format: Article (Journal)
Language:English
Published: 2001
In: Organometallics
Year: 2001, Volume: 20, Issue: 24, Pages: 5005-5007
ISSN:1520-6041
DOI:10.1021/om010753
Online Access:Verlag, Volltext: http://dx.doi.org/10.1021/om010753+
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Author Notes:Markus Enders, Pablo Fernández, Gunter Ludwig, Hans Pritzkow
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Summary:Cyclopentadienyl ligands functionalized by quinoline or N,N-dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5-8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly active, temperature-stable catalysts for the polymerization of ethylene.
Item Description:Gesehen am 19.02.2018
Physical Description:Online Resource
ISSN:1520-6041
DOI:10.1021/om010753

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