A new receptor of aromatic Carboxylates based on a trismacrocyclic complex of Copper(II) and operating according to the molecular recognition principle
The reaction of mono-, bis-, and trismacrocyclic complexes of copper(II) with aromatic carboxylates was studied by a spectrophotometric method. It was shown that the largest spectral changes are observed during the reaction of the trinuclear complex with its complementary benzene-1,3,5-tricarboxylat...
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| Main Author: | |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2001
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| In: |
Theoretical and experimental chemistry
Year: 2001, Volume: 37, Issue: 4, Pages: 236-240 |
| ISSN: | 1573-935X |
| DOI: | 10.1023/A:1012576411929 |
| Online Access: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1023/A:1012576411929 Verlag, Pay-per-use, Volltext: https://link.springer.com/article/10.1023/A:1012576411929 
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| Author Notes: | P. Comba, Ya. D. Lampeka, A. I. Prikhod'ko, and H. Pritzkow |
| Summary: | The reaction of mono-, bis-, and trismacrocyclic complexes of copper(II) with aromatic carboxylates was studied by a spectrophotometric method. It was shown that the largest spectral changes are observed during the reaction of the trinuclear complex with its complementary benzene-1,3,5-tricarboxylate anion. The receptor also differentiates regioselectively between the isomers of phthalic acids. The crystal structure of the 1 : 2 adduct of the trismacrocyclic complex of copper with benzenetricarboxylate was determined. |
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| Item Description: | Gesehen am 07.03.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1573-935X |
| DOI: | 10.1023/A:1012576411929 |