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Cleavage of the N2 triple bond by the Ti dimer: a route to molecular materials for dinitrogen activation?

The Ti dimer is fairly weakly bound, but highly reactive, and completely cleaves the strong N2 triple bond in just one step without activation energy (see scheme; Ti red, N blue).

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Bibliographic Details
Main Authors: Himmel, Hans-Jörg (Author) , Hübner, Olaf (Author) , Klopper, Wim (Author) , Manceron, Laurent (Author)
Format: Article (Journal)
Language:English
Published: 2006
In: Angewandte Chemie. International edition
Year: 2006, Volume: 45, Issue: 17, Pages: 2799-2802
ISSN:1521-3773
DOI:10.1002/anie.200503709
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/anie.200503709
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/anie.200503709/full
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Author Notes:Hans-Jörg Himmel, Olaf Hübner, Wim Klopper, Laurent Manceron
Description
Summary:The Ti dimer is fairly weakly bound, but highly reactive, and completely cleaves the strong N2 triple bond in just one step without activation energy (see scheme; Ti red, N blue).
Item Description:Gesehen am 14.03.2018
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.200503709

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