Bismuthanides and bismuthanediides: synthesis and structural characterization of [R2Bi]− and [(RBi)12Na21]3− salts with bulky Silyl substituents
The reaction of bismuth trihalides with the bulky alkali metal silanides [(THF)3LiSi(SiMe3)3] and [(THF)2NaSi(CMe3)3] affords the cyclotetrabismuthanes (RBi)41 and 3, the alkali metal bismuthanides [Li(THF)4][Bi{Si(SiMe3)3}2]...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
30 August 2002
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| In: |
European journal of inorganic chemistry
Year: 2002, Issue: 10, Pages: 2643-2647 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/1099-0682(200210)2002:10<2643::AID-EJIC2643>3.0.CO;2-2 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/1099-0682(200210)2002:10<2643::AID-EJIC2643>3.0.CO;2-2 Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/1099-0682(200210)2002:10<2643::AID-EJIC2643>3.0.CO;2-2/full |
| Author Notes: | Gerald Linti, Wolfgang Köstler, Hans Pritzkow |
| Summary: | The reaction of bismuth trihalides with the bulky alkali metal silanides [(THF)3LiSi(SiMe3)3] and [(THF)2NaSi(CMe3)3] affords the cyclotetrabismuthanes (RBi)41 and 3, the alkali metal bismuthanides [Li(THF)4][Bi{Si(SiMe3)3}2]... |
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| Item Description: | Gesehen am 16.03.2018 Im Titel ist "2", "12", "21" tiefgestellt, "3" hochgestellt |
| Physical Description: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/1099-0682(200210)2002:10<2643::AID-EJIC2643>3.0.CO;2-2 |