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Tri(supersilyl)dialanyl (tBu3Si)3Al2• and tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al3•: new stable radicals of a group 13 element from thermolysis of (tBu3Si)4Al2

The thermolysis of tetra(supersilyl)dialane R*2Al−AlR*2 (R* = SitBu3 = Supersilyl) in heptane or cyclohexane at 50 °C leads under Al−Al dissociation reversibly to monoalanyl radicals [R*2Al]•, which could...

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Bibliographic Details
Main Authors: Wiberg, Nils (Author) , Blank, Thomas (Author) , Kaim, Wolfgang (Author) , Schwederski, Brigitte (Author) , Linti, Gerald W. (Author)
Format: Article (Journal)
Language:English
Published: 4 July 2000
In: European journal of inorganic chemistry
Year: 2000, Issue: 7, Pages: 1475-1481
ISSN:1099-0682
DOI:10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N
Verlag, Volltext: http://onlinelibrary.wiley.com/doi/10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N/full
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Author Notes:Nils Wiberg, Thomas Blank, Wolfgang Kaim, Brigitte Schwederski, Gerald Linti
Description
Summary:The thermolysis of tetra(supersilyl)dialane R*2Al−AlR*2 (R* = SitBu3 = Supersilyl) in heptane or cyclohexane at 50 °C leads under Al−Al dissociation reversibly to monoalanyl radicals [R*2Al]•, which could...
Item Description:Gesehen am 16.03.2018
Im Titel ist "2", "3", "4" tiefgestellt, "•" hochgestellt
Physical Description:Online Resource
ISSN:1099-0682
DOI:10.1002/1099-0682(200007)2000:7<1475::AID-EJIC1475>3.0.CO;2-N

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