Facile synthesis and crystal structure of aGa22R8 cluster

A new metalloid cluster Ga22R8 with a central gallium atom exhibiting an unusual coordination number of 13 and the gallatetrahedrane Ga4R4 are obtained by reaction of ‘GaI’ with the lithium tris(trimethylsilyl)germanide Li(thf)3R.

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Bibliographic Details
Main Authors: Linti, Gerald W. (Author) , Rodig, Alexander (Author)
Format: Article (Journal)
Language:English
Published: 17 January 2000
In: Chemical communications
Year: 2000, Issue: 2, Pages: 127-128
ISSN:1364-548X
DOI:10.1039/A907039G
Online Access:Verlag, Volltext: http://dx.doi.org/10.1039/A907039G
Verlag, Volltext: http://pubs.rsc.org/en/content/articlelanding/2000/cc/a907039g
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Author Notes:Gerald Linti, Alexander Rodig
Description
Summary:A new metalloid cluster Ga22R8 with a central gallium atom exhibiting an unusual coordination number of 13 and the gallatetrahedrane Ga4R4 are obtained by reaction of ‘GaI’ with the lithium tris(trimethylsilyl)germanide Li(thf)3R.
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Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/A907039G