Substrate‐directed diastereoselective hydroformylation: key step for the assembly of polypropionate subunits
Abstract o-DPPB-Directed hydroformylation could serve as a key step for the construction of bifunctionalized stereotriad building blocks, which form the basis of polyketide natural products (see scheme). The prepared building blocks are well suited to permit polyketide chain extensions into both dir...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
24 September 1999
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| In: |
Chemistry - a European journal
Year: 1999, Volume: 5, Issue: 10, Pages: 2819-2827 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/(SICI)1521-3765(19991001)5:10<2819::AID-CHEM2819>3.0.CO;2-Z |
| Online Access: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/(SICI)1521-3765(19991001)5:10<2819::AID-CHEM2819>3.0.CO;2-Z Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3765%2819991001%295%3A10%3C2819%3A%3AAID-CHEM2819%3E3.0.CO%3B2-Z |
| Author Notes: | Bernhard Breit, Mario Dauber, and Klaus Harms |
| Summary: | Abstract o-DPPB-Directed hydroformylation could serve as a key step for the construction of bifunctionalized stereotriad building blocks, which form the basis of polyketide natural products (see scheme). The prepared building blocks are well suited to permit polyketide chain extensions into both directions of the main chain. o-DPPB=ortho-diphenylphosphanylbenzoyl. |
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| Item Description: | Gesehen am 21.03.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/(SICI)1521-3765(19991001)5:10<2819::AID-CHEM2819>3.0.CO;2-Z |