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Domino hydroformylation‐Wittig reactions

Abstract Methallyl and homomethallyl alcohols can undergo stereoselective hydroformylation-Wittig and hydroformylation-Wittig-hydrogenation reactions in one-pot domino processes. This sequential transformation allows the formation of C-C bonds and the generation of a new stereogenic center, and give...

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Bibliographic Details
Main Authors: Breit, Bernhard (Author) , Zahn, Stephan K. (Author)
Format: Article (Journal)
Language:English
Published: 26 March 1999
In: Angewandte Chemie. International edition
Year: 1999, Volume: 38, Issue: 7, Pages: 969-971
ISSN:1521-3773
DOI:10.1002/(SICI)1521-3773(19990401)38:7<969::AID-ANIE969>3.0.CO;2-4
Online Access:Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/(SICI)1521-3773(19990401)38:7<969::AID-ANIE969>3.0.CO;2-4
Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/%28SICI%291521-3773%2819990401%2938%3A7%3C969%3A%3AAID-ANIE969%3E3.0.CO%3B2-4
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Author Notes:Bernhard Breit and Stephan K. Zahn
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Summary:Abstract Methallyl and homomethallyl alcohols can undergo stereoselective hydroformylation-Wittig and hydroformylation-Wittig-hydrogenation reactions in one-pot domino processes. This sequential transformation allows the formation of C-C bonds and the generation of a new stereogenic center, and gives preparatively interesting compounds [Eq. (a)]. The reaction products are obtained in satisfactory to good yields and in diastereoselectivities of 90:10 to >98:2. CDG=catalyst-directing group; R'=H; R''=OEt, Me.
Item Description:Gesehen am 21.03.2018
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/(SICI)1521-3773(19990401)38:7<969::AID-ANIE969>3.0.CO;2-4

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