Hydroamination/hydrosilylation sequence catalyzed by titanium complexes
A single precatalyst is used for the sequential combination of the Ti-catalyzed hydroamination of alkynes with the Ti-catalyzed hydrosilylation of imines. In this way alkynes and primary amines are converted efficiently into secondary amines in a fully catalytic one-pot process (see scheme).
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
3 May 2005
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| In: |
Angewandte Chemie. International edition
Year: 2005, Volume: 44, Issue: 19, Pages: 2951-2954 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200462250 |
| Online Access: | Verlag, Pay-per-use, Volltext: http://dx.doi.org/10.1002/anie.200462250 Verlag, Pay-per-use, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200462250 
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| Author Notes: | Andreas Heutling, Frauke Pohlki, Igor Bytschkov, and Sven Doye |
| Summary: | A single precatalyst is used for the sequential combination of the Ti-catalyzed hydroamination of alkynes with the Ti-catalyzed hydrosilylation of imines. In this way alkynes and primary amines are converted efficiently into secondary amines in a fully catalytic one-pot process (see scheme). |
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| Item Description: | Gesehen am 26.03.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.200462250 |