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Synthesis and structures of the triple-decker type complexes CpCo([mu]1,3-C3B2Me5)MX2L (M = Rh and Ir; X = Cl and Br; L = Me2SO and PPh3)

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The dimeric triple-decker type halides [CpCo(μ-1,3-C3B2Me5)MX2]2 (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(μ-1,3-C3B2Me5)M(L)X2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone...

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Bibliographic Details
Main Authors: Romanov, Alexander S. (Author) , Siebert, Walter (Author)
Format: Article (Journal)
Language:English
Published: September 2012
In: Journal of organometallic chemistry
Year: 2012, Volume: 715, Pages: 136-140
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2012.06.003
Online Access:Verlag, Volltext: http://dx.doi.org/10.1016/j.jorganchem.2012.06.003
Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X12003294
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Author Notes:Alexander S. Romanov, Dmitry V. Muratov, Mikhail Yu. Antipin, Walter Siebert, Alexander R. Kudinov
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Summary:The dimeric triple-decker type halides [CpCo(μ-1,3-C3B2Me5)MX2]2 (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(μ-1,3-C3B2Me5)M(L)X2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5-12 were confirmed by X-ray diffraction.
Item Description:Im Titel ist mu als griechischer Buchstabe dargestellt
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Physical Description:Online Resource
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2012.06.003

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