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Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N-N) unit.

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Bibliographic Details
Main Authors: Gehrmann, Thorsten (Author) , Kruck, Matthias (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 25 Jan 2012
In: Chemical communications
Year: 2012, Volume: 48, Issue: 18, Pages: 2397-2399
ISSN:1364-548X
DOI:10.1039/C2CC17594K
Online Access:Verlag, Volltext: http://dx.doi.org/10.1039/C2CC17594K
Verlag, Volltext: http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc17594k
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Author Notes:Thorsten Gehrmann, Matthias Kruck, Hubert Wadepohl and Lutz H. Gade
Description
Summary:Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN2(N-N) unit.
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Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C2CC17594K

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