Site-selective resonant Auger spectroscopy of iso-dichloroethylene at the carbon K-edge
This study focuses on the two C1s-to-LUMO (lowest unoccupied molecular orbital) excitations of the iso-dichloroethylene (H2CCCl2) and the subsequent Auger decay. We investigate the effect of the two different carbon core excitations on the population of the cation produced after electronic relaxatio...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
September 2012
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| In: |
Journal of electron spectroscopy and related phenomena
Year: 2012, Volume: 185, Issue: 8, Pages: 252-258 |
| ISSN: | 0368-2048 |
| DOI: | 10.1016/j.elspec.2012.06.005 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1016/j.elspec.2012.06.005 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0368204812000606 
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| Author Notes: | D. Céolin, O. Travnikova, Z. Bao, F.F. Guimarães, M.S. da Costa, Y. Velkov, N. Sisourat, S. Carniato, M. Simon, M.N. Piancastelli |
| Summary: | This study focuses on the two C1s-to-LUMO (lowest unoccupied molecular orbital) excitations of the iso-dichloroethylene (H2CCCl2) and the subsequent Auger decay. We investigate the effect of the two different carbon core excitations on the population of the cation produced after electronic relaxation. The resonant Auger spectra are interpreted by comparison to the valence shells photoionization spectrum and with the help of theoretical calculations. Several consequences of the core-hole localization on the electronic decay are observed. In particular, the resonant excitation of the C1s(CH2) to the LUMO leads to a large intensity increase in the region of the first satellite state, whereas no dramatic changes are observed for the C1s(CCl2) excitation. |
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| Item Description: | Gesehen am 08.05.2018 |
| Physical Description: | Online Resource |
| ISSN: | 0368-2048 |
| DOI: | 10.1016/j.elspec.2012.06.005 |