Metal-free nitrile diboration through activation by an electron-rich diborane
Diboration of unsaturated organic compounds is an extremely useful reaction in synthetic chemistry. Herein, we report the first diboration of a nitrile by an electron-rich diborane, mediated by an electrophilic borane. The reaction is metal-free, and all of the reagents are readily available.
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
19 July 2017
|
| In: |
Angewandte Chemie. International edition
Year: 2017, Volume: 56, Issue: 38, Pages: 11645-11648 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201706001 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/anie.201706001 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201706001 
|
| Author Notes: | Markus Frick, Elisabeth Kaifer, and Hans-Jörg Himmel |
| Summary: | Diboration of unsaturated organic compounds is an extremely useful reaction in synthetic chemistry. Herein, we report the first diboration of a nitrile by an electron-rich diborane, mediated by an electrophilic borane. The reaction is metal-free, and all of the reagents are readily available. |
|---|---|
| Item Description: | Gesehen am 08.05.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201706001 |