Regular high-nuclearity species from square building blocks: a triangular 3 × [2 × 2] Ni12 complex generated by the self-assembly of three [2 × 2] Ni4 golecular grids
A dodecanuclear 3 × [2 × 2] nickel(II) complex has been obtained via the self-association of three tetranuclear [2 × 2] molecular grids. X-ray diffraction shows a “propeller-like” structure of the [Ni4]3 scaffold with a central μ3-hydroxide. The dodecanuclear species remains stable in solution and c...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
July 5, 2012
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| In: |
Inorganic chemistry
Year: 2012, Volume: 51, Issue: 14, Pages: 7445-7447 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic300902z |
| Online Access: | Verlag, kostenfrei, Volltext: http://dx.doi.org/10.1021/ic300902z Verlag, kostenfrei, Volltext: https://doi.org/10.1021/ic300902z 
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| Author Notes: | Yurii S. Moroz, Serhiy Demeshko, Matti Haukka, Andriy Mokhir, Utpal Mitra, Michael Stocker, Paul Müller, Franc Meyer, Igor O. Fritsky |
| Summary: | A dodecanuclear 3 × [2 × 2] nickel(II) complex has been obtained via the self-association of three tetranuclear [2 × 2] molecular grids. X-ray diffraction shows a “propeller-like” structure of the [Ni4]3 scaffold with a central μ3-hydroxide. The dodecanuclear species remains stable in solution and can be deposited without decomposition on highly ordered pyrolytic graphite surfaces. |
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| Item Description: | Gesehen am 15.05.2018 Die Zahlen bei Ni12, Ni4 sind tiefgestellt |
| Physical Description: | Online Resource |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic300902z |