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Cryptate complexes with the potential for CO2 activation: quantum chemical predictions and synthetic efforts

In this work we discuss the possibility of CO2 activation by novel magnesium and zinc cryptate complexes. The choice of the complexes is partially based on the results of studies on CO2 fixation by amidometal complexes and partially inspired by the mode of action of the RuBisCO enzyme. Quantum chemi...

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Bibliographic Details
Main Authors: Fuchs, Alexander (Author) , Kaifer, Elisabeth (Author) , Wadepohl, Hubert (Author) , Himmel, Hans-Jörg (Author)
Format: Article (Journal)
Language:English
Published: 01 August 2012
In: European journal of inorganic chemistry
Year: 2012, Issue: 25, Pages: 4020-4028
ISSN:1099-0682
DOI:10.1002/ejic.201200072
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201200072
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201200072
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Author Notes:Alexander Fuchs, Elisabeth Kaifer, Hubert Wadepohl, and Hans-Jörg Himmel
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Summary:In this work we discuss the possibility of CO2 activation by novel magnesium and zinc cryptate complexes. The choice of the complexes is partially based on the results of studies on CO2 fixation by amidometal complexes and partially inspired by the mode of action of the RuBisCO enzyme. Quantum chemical calculations underline the potential of this new approach, and argue for reversible CO2 activation and bonding to the cryptand complexes. We then report on the first steps towards an experimental realization and its limitations. A new cryptand molecule (15-oxa-1,4,7,10-tetraazabicyclo[5.5.5]heptadecane) was synthesized featuring two secondary amino functions. It was shown to give stable complexes with lithium and zinc ions, in which the metal ions are captured inside the cryptand void. Unfortunately, the last step in the preparation of the targeted complex for CO2 fixation, namely deprotonation of both secondary amino groups, was not achieved.
Item Description:Gesehen am 28.05.2018
Physical Description:Online Resource
ISSN:1099-0682
DOI:10.1002/ejic.201200072

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