Incorporation of a redox-active bis(guanidine) in low-dimensional tin and lead Iodide structures
Redox-active, protonated guanidines are incorporated in tin and lead iodide structures to protect the metal atoms from being oxidized and to thereby increase the stability of these materials. They could serve as preferred place of attack for incoming dioxygen, reducing it to redox-inactive water, wh...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2017
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| In: |
European journal of inorganic chemistry
Year: 2017, Issue: 47, Pages: 5539-5544 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201700840 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201700840 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201700840 
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| Author Notes: | Hendrik Herrmann, Petra Walter, Elisabeth Kaifer, and Hans-Jörg Himmel |
| Summary: | Redox-active, protonated guanidines are incorporated in tin and lead iodide structures to protect the metal atoms from being oxidized and to thereby increase the stability of these materials. They could serve as preferred place of attack for incoming dioxygen, reducing it to redox-inactive water, while being themselves oxidized to a stable dication without significant structural changes. This work focuses on the synthesis and bulk characterization of two first examples for tin and lead iodide materials with redox-active guanidines. |
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| Item Description: | First published: 07 September 2017 Gesehen am 11.06.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201700840 |