Incorporation of a redox-active bis(guanidine) in low-dimensional tin and lead Iodide structures
Redox-active, protonated guanidines are incorporated in tin and lead iodide structures to protect the metal atoms from being oxidized and to thereby increase the stability of these materials. They could serve as preferred place of attack for incoming dioxygen, reducing it to redox-inactive water, wh...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2017
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| In: |
European journal of inorganic chemistry
Year: 2017, Heft: 47, Pages: 5539-5544 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.201700840 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/ejic.201700840 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201700840 
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| Verfasserangaben: | Hendrik Herrmann, Petra Walter, Elisabeth Kaifer, and Hans-Jörg Himmel |
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| 520 | |a Redox-active, protonated guanidines are incorporated in tin and lead iodide structures to protect the metal atoms from being oxidized and to thereby increase the stability of these materials. They could serve as preferred place of attack for incoming dioxygen, reducing it to redox-inactive water, while being themselves oxidized to a stable dication without significant structural changes. This work focuses on the synthesis and bulk characterization of two first examples for tin and lead iodide materials with redox-active guanidines. | ||
| 650 | 4 | |a Guanidines | |
| 650 | 4 | |a Iodides | |
| 650 | 4 | |a Lead | |
| 650 | 4 | |a Organic electron donors | |
| 650 | 4 | |a Perovskite phases | |
| 650 | 4 | |a Redox chemistry | |
| 650 | 4 | |a Tin | |
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| 787 | 0 | 8 | |i Ergänzung |a Herrmann, Hendrik Hans |t Hans-Jörg Himmel et al., incorporation of a redox-active bis(guanidine) in low-dimensional tin and lead Iodide structures |d 2017 |w (DE-627)1766110355 |
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