A readily accessible PNP pincer ligand with a pyrrole backbone and its NiI/II chemistry
The novel chelating PNP pincer ligand 2,5-bis((diphenylphosphino)methyl)-1H-pyrrole (1) was prepared and its nickel coordination chemistry explored. The reaction with Ni(COD)2 led to a diamagnetic dinuclear nickel(I) complex (4) which was also obtained by the reaction of the square planar NiII compl...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2012
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| In: |
Dalton transactions
Year: 2012, Volume: 41, Issue: 46, Pages: 14028-14030 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/C2DT32199H |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1039/C2DT32199H Verlag, Volltext: http://pubs.rsc.org/en/content/articlelanding/2012/dt/c2dt32199h 
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| Author Notes: | Nora Grüger, Hubert Wadepohl and Lutz H. Gade |
| Summary: | The novel chelating PNP pincer ligand 2,5-bis((diphenylphosphino)methyl)-1H-pyrrole (1) was prepared and its nickel coordination chemistry explored. The reaction with Ni(COD)2 led to a diamagnetic dinuclear nickel(I) complex (4) which was also obtained by the reaction of the square planar NiII complexes [(PNP-Ph2)NiX] (X = Cl (2), X = I (3)) with Li(Et3BH). |
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| Item Description: | Die Zahlen I/II sind im Titel hochgestellt Published on 12 October 2012 Gesehen am 14.06.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/C2DT32199H |