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A readily accessible PNP pincer ligand with a pyrrole backbone and its NiI/II chemistry

The novel chelating PNP pincer ligand 2,5-bis((diphenylphosphino)methyl)-1H-pyrrole (1) was prepared and its nickel coordination chemistry explored. The reaction with Ni(COD)2 led to a diamagnetic dinuclear nickel(I) complex (4) which was also obtained by the reaction of the square planar NiII compl...

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Bibliographische Detailangaben
Hauptverfasser: Grüger, Nora (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Gade, Lutz H. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2012
In: Dalton transactions
Year: 2012, Jahrgang: 41, Heft: 46, Pages: 14028-14030
ISSN:1477-9234
DOI:10.1039/C2DT32199H
Online-Zugang:Verlag, Volltext: http://dx.doi.org/10.1039/C2DT32199H
Verlag, Volltext: http://pubs.rsc.org/en/content/articlelanding/2012/dt/c2dt32199h
Volltext
Verfasserangaben:Nora Grüger, Hubert Wadepohl and Lutz H. Gade
Beschreibung
Zusammenfassung:The novel chelating PNP pincer ligand 2,5-bis((diphenylphosphino)methyl)-1H-pyrrole (1) was prepared and its nickel coordination chemistry explored. The reaction with Ni(COD)2 led to a diamagnetic dinuclear nickel(I) complex (4) which was also obtained by the reaction of the square planar NiII complexes [(PNP-Ph2)NiX] (X = Cl (2), X = I (3)) with Li(Et3BH).
Beschreibung:Die Zahlen I/II sind im Titel hochgestellt
Published on 12 October 2012
Gesehen am 14.06.2018
Beschreibung:Online Resource
ISSN:1477-9234
DOI:10.1039/C2DT32199H

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