Triflic acid catalyzed oxidative lactonization and diacetoxylation of alkenes using peroxyacids as oxidants

A clean and efficient diacetoxylation reaction of alkenes catalyzed by triflic acid using commercially available peroxyacids as the oxidants has been developed. This method was also applied in oxidative lactonizations of unsaturated carboxylic acids in good to high yields.

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Bibliographic Details
Main Authors: Kang, Yanbiao (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 2012
In: The journal of organic chemistry
Year: 2012, Volume: 77, Issue: 3, Pages: 1610-1615
ISSN:1520-6904
DOI:10.1021/jo202491y
Online Access:Verlag, Volltext: http://dx.doi.org/10.1021/jo202491y
Verlag, Volltext: https://doi.org/10.1021/jo202491y
Verlag, Volltext: https://pubs.acs.org/doi/pdf/10.1021/jo202491y
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Author Notes:Yan-Biao Kang, Lutz H. Gade
Description
Summary:A clean and efficient diacetoxylation reaction of alkenes catalyzed by triflic acid using commercially available peroxyacids as the oxidants has been developed. This method was also applied in oxidative lactonizations of unsaturated carboxylic acids in good to high yields.
Item Description:Publication date (web): January 9, 2012
Gesehen am 20.06.2018
Physical Description:Online Resource
ISSN:1520-6904
DOI:10.1021/jo202491y