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Syntheses of the hexahydroindene cores of indanomycin and stawamycin by combinations of iridium-catalyzed asymmetric allylic alkylations and intramolecular Diels-Alder reactions

Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reacti...

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Bibliographic Details
Main Authors: Gärtner, Martin (Author) , Förster, Sebastian (Author) , Helmchen, Günter (Author)
Format: Article (Journal)
Language:English
Published: 2013
In: Chemistry - a European journal
Year: 2012, Volume: 19, Issue: 1, Pages: 400-405
ISSN:1521-3765
DOI:10.1002/chem.201202822
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/chem.201202822
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201202822
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Author Notes:Martin Gärtner, Gedu Satyanarayana, Sebastian Förster and Günter Helmchen
Description
Summary:Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reaction.
Item Description:First published: 23 November 2012
Gesehen am 21.06.2018
Physical Description:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201202822

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