Syntheses of the hexahydroindene cores of indanomycin and stawamycin by combinations of iridium-catalyzed asymmetric allylic alkylations and intramolecular Diels-Alder reactions
Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reacti...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2013
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| In: |
Chemistry - a European journal
Year: 2012, Jahrgang: 19, Heft: 1, Pages: 400-405 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201202822 |
| Online-Zugang: | Verlag, Volltext: http://dx.doi.org/10.1002/chem.201202822 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201202822 
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| Verfasserangaben: | Martin Gärtner, Gedu Satyanarayana, Sebastian Förster and Günter Helmchen |
MARC
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| 520 | |a Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki-Miyaura coupling, and an intramolecular Diels-Alder reaction. | ||
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