A palladium-catalyzed one-pot procedure for the regioselective dimerization and cyanation of indoles
A one-pot method for the regioselective dimerization and cyanation of indoles has been developed. The reaction uses safe and nontoxic K4[Fe(CN)6]·3H2O as the cyanating agent which introduces selectively a cyano group into the 3-position of biindoles with high efficiency.
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| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
6 February 2012
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| In: |
Tetrahedron letters
Year: 2012, Volume: 53, Issue: 15, Pages: 1900-1904 |
| ISSN: | 1873-3581 |
| DOI: | 10.1016/j.tetlet.2012.01.129 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1016/j.tetlet.2012.01.129 Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S0040403912001864 
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| Author Notes: | Ebrahim Kianmehr, Mohammad Ghanbari, Nasser Faghih, Frank Rominger |
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| 520 | |a A one-pot method for the regioselective dimerization and cyanation of indoles has been developed. The reaction uses safe and nontoxic K4[Fe(CN)6]·3H2O as the cyanating agent which introduces selectively a cyano group into the 3-position of biindoles with high efficiency. | ||
| 650 | 4 | |a C-C bond formation | |
| 650 | 4 | |a Cyanation | |
| 650 | 4 | |a Homogeneous catalysis | |
| 650 | 4 | |a Indoles | |
| 650 | 4 | |a Palladium | |
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