Fire and ice: a gold(III) monohydride

Good as gold: Gold hydrides were long considered unstable. In the past few years reports have appeared on not only the stable NHC gold(I) monohydride complex 1 (see structure; NHC=N-heterocyclic carbene) but also a dinuclear gold(I) hydride and most recently the gold(III) monohydride complex 2 with...

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Bibliographic Details
Main Author: Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: November 26, 2012
In: Angewandte Chemie. International edition
Year: 2012, Volume: 51, Issue: 52, Pages: 12935-12936
ISSN:1521-3773
DOI:10.1002/anie.201208603
Online Access:Verlag, Volltext: http://dx.doi.org/10.1002/anie.201208603
Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201208603
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Author Notes:A. Stephen K. Hashmi
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Summary:Good as gold: Gold hydrides were long considered unstable. In the past few years reports have appeared on not only the stable NHC gold(I) monohydride complex 1 (see structure; NHC=N-heterocyclic carbene) but also a dinuclear gold(I) hydride and most recently the gold(III) monohydride complex 2 with a C-N-C pincer ligand. One can expect new and important impulses for inorganic and organometallic chemistry and homogeneous gold catalysis.
Item Description:Gesehen am 04.09.2018
Physical Description:Online Resource
ISSN:1521-3773
DOI:10.1002/anie.201208603