Cobalt alkyl complexes of a new family of chiral 1,3-Bis(2-pyridylimino)isoindolates and their application in asymmetric hydrosilylation
Synopsis: A new family of chiral 1,3-bis(2-pyridylimino)isoindolate ligands with various substitution patterns was prepared using achiral starting materials. Their cobalt alkyl complexes were synthesized and characterized. The application of this enantiomerically pure compounds in the asymmetric hyd...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
November 12, 2012
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| In: |
Inorganic chemistry
Year: 2012, Volume: 51, Issue: 23, Pages: 12948-12958 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic3020749 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1021/ic3020749
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| Author Notes: | Désirée C. Sauer, Hubert Wadepohl, and Lutz H. Gade |
| Summary: | Synopsis: A new family of chiral 1,3-bis(2-pyridylimino)isoindolate ligands with various substitution patterns was prepared using achiral starting materials. Their cobalt alkyl complexes were synthesized and characterized. The application of this enantiomerically pure compounds in the asymmetric hydrosilylation of ketones was tested giving the corresponding alcohols in high yields and enantioselectivity. |
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| Item Description: | Gesehen am 13.09.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic3020749 |