Unexpected synthesis of 1,3,4-oxadiazines using extraordinary effect of SBA-Pr-SO3H as the nano-catalyst
Unexpected synthesis of 1,3,4-oxadiazines has been accomplished through three-component reaction of cyclohexyl isocyanide, hydrazide derivatives and cyclic ketones in the presence of a catalytic amount of SBA−Pr-SO3H as an efficient catalyst. A range of spirooxadiazine derivatives were synthesized i...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
27 April 2017
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| In: |
ChemistrySelect
Year: 2017, Volume: 2, Issue: 12, Pages: 3496-3499 |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.201601862 |
| Online Access: | Verlag, Volltext: http://dx.doi.org/10.1002/slct.201601862 Verlag, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201601862 
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| Author Notes: | Vaezeh Fathi Vavsari, Ghodsi Mohammadi Ziarani, Saeed Balalaie, Alireza Badiei, Farhad Golmohammadi, Sorour Ramezanpour, and Frank Rominger |
| Summary: | Unexpected synthesis of 1,3,4-oxadiazines has been accomplished through three-component reaction of cyclohexyl isocyanide, hydrazide derivatives and cyclic ketones in the presence of a catalytic amount of SBA−Pr-SO3H as an efficient catalyst. A range of spirooxadiazine derivatives were synthesized in high yields in a concise way. The same three-component reaction in the presence of other acidic catalysts led to the synthesis of hydrazino amides. The formation of 1,3,4-oxadiazines is related to the pore size and structure of SBA−Pr-SO3H which spatial orientation of intermediate onto it leads to the formation of the oxadiazine ring. |
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| Item Description: | Die 3 in SBA-Pr-SO3H ist im Titel tiefgestellt Gesehen am 26.09.2018 |
| Physical Description: | Online Resource |
| ISSN: | 2365-6549 |
| DOI: | 10.1002/slct.201601862 |