New transmetalation reagents for the gold-catalyzed visible light-enabled C(sp or sp2)-C(sp2) cross-coupling with aryldiazonium salts in the absence of a photosensitizer
The scope of photosensitizer-free visible light-driven gold-catalyzed cross-coupling was evaluated by a wide variety of organoboron and organosilicon species using four equivalents of aryldiazonium salts and (4-CF3-C6H4)3PAuCl in MeOH. In addition, a C(sp or sp2)-C(sp2) cross-coupling of organotrime...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
10 Nov 2018
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| In: |
Chemical communications
Year: 2018, Volume: 54, Issue: 98, Pages: 13802-13804 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C8CC08227H |
| Online Access: | Resolving-System, Volltext: http://dx.doi.org/10.1039/C8CC08227H Verlag, Volltext: https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc08227h 
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| Author Notes: | Sina Witzel, Kohei Sekine, Matthias Rudolph and A. Stephen K. Hashmi |
| Summary: | The scope of photosensitizer-free visible light-driven gold-catalyzed cross-coupling was evaluated by a wide variety of organoboron and organosilicon species using four equivalents of aryldiazonium salts and (4-CF3-C6H4)3PAuCl in MeOH. In addition, a C(sp or sp2)-C(sp2) cross-coupling of organotrimethylsilanes and aryldiazonium salts was investigated. The reactions can be conducted under very mild reaction conditions, with a reduced amount of aryldiazonium salt (1.2 equiv.) by using a catalytic amount of Ph3PAuNTf2 in MeCN under irradiation with blue LEDs at room temperature. |
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| Item Description: | Im Titel ist die Ziffer 2 jeweils hochgestellt Gesehen am 11.12.2018 |
| Physical Description: | Online Resource |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C8CC08227H |