Buchumschlag

Dinuclear NHC gold(I) allenyl and propargyl complexes: an experimental and theoretical study

The synthesis and isolation of the dinuclear NHC gold(I) allene-1,3-diyl complex Ph(IPrAu)C═C═CH(AuIPr) and the dinuclear NHC gold(I) propyne-1,3-diyl complex Ph(IPrAu)CH–C≡C–Au(IPr) are presented. The monoprotodeauration reactions of these dinuclear complexes selectively led to the mononuclear orga...

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Hauptverfasser: Zargaran, Poorya (VerfasserIn) , Mulks, Florian (VerfasserIn) , Gall, Samuel (VerfasserIn) , Rudolph, Matthias (VerfasserIn) , Rominger, Frank (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: March 6, 2019
In: Organometallics
Year: 2019, Jahrgang: 38, Heft: 7, Pages: 1524-1533
ISSN:1520-6041
DOI:10.1021/acs.organomet.8b00943
Online-Zugang:Verlag, Volltext: https://doi.org/10.1021/acs.organomet.8b00943
Volltext
Verfasserangaben:Poorya Zargaran, Florian. F. Mulks, Samuel Gall, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
Beschreibung
Zusammenfassung:The synthesis and isolation of the dinuclear NHC gold(I) allene-1,3-diyl complex Ph(IPrAu)C═C═CH(AuIPr) and the dinuclear NHC gold(I) propyne-1,3-diyl complex Ph(IPrAu)CH–C≡C–Au(IPr) are presented. The monoprotodeauration reactions of these dinuclear complexes selectively led to the mononuclear organogold complexes Ph(IPrAu)C═C═CH2 and PhCH2–C≡C–Au(IPr), respectively. The experimental structures and the obtained analytical data of the synthesized complexes as well as the results of a computational DFT study of their thermodynamic stability are compared systematically.
Beschreibung:Gesehen am 13.05.2019
Beschreibung:Online Resource
ISSN:1520-6041
DOI:10.1021/acs.organomet.8b00943

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