Dinuclear NHC gold(I) allenyl and propargyl complexes: an experimental and theoretical study
The synthesis and isolation of the dinuclear NHC gold(I) allene-1,3-diyl complex Ph(IPrAu)C═C═CH(AuIPr) and the dinuclear NHC gold(I) propyne-1,3-diyl complex Ph(IPrAu)CH–C≡C–Au(IPr) are presented. The monoprotodeauration reactions of these dinuclear complexes selectively led to the mononuclear orga...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
March 6, 2019
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| In: |
Organometallics
Year: 2019, Volume: 38, Issue: 7, Pages: 1524-1533 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.8b00943 |
| Online Access: | Verlag, Volltext: https://doi.org/10.1021/acs.organomet.8b00943 |
| Author Notes: | Poorya Zargaran, Florian. F. Mulks, Samuel Gall, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
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| 245 | 1 | 0 | |a Dinuclear NHC gold(I) allenyl and propargyl complexes |b an experimental and theoretical study |c Poorya Zargaran, Florian. F. Mulks, Samuel Gall, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
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| 520 | |a The synthesis and isolation of the dinuclear NHC gold(I) allene-1,3-diyl complex Ph(IPrAu)C═C═CH(AuIPr) and the dinuclear NHC gold(I) propyne-1,3-diyl complex Ph(IPrAu)CH–C≡C–Au(IPr) are presented. The monoprotodeauration reactions of these dinuclear complexes selectively led to the mononuclear organogold complexes Ph(IPrAu)C═C═CH2 and PhCH2–C≡C–Au(IPr), respectively. The experimental structures and the obtained analytical data of the synthesized complexes as well as the results of a computational DFT study of their thermodynamic stability are compared systematically. | ||
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