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Cover feature: bowl shaped monodentate phosphines by condensation of Imidazole units with boranes

The cover picture shows a new class of chiral phosphine ligands bearing three imidazole units bridged by boranes. The bowl shaped, C3 symmetric molecules are obtained by a simple condensation procedure. The steric bulk of these monodentate ligands can easily be adjusted over a large range by the use...

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Bibliographic Details
Main Authors: Schall, Helene (Author) , Fritz, Olaf (Author) , Schikora, Margot (Author) , Elias, Jana (Author) , Pritzkow, Hans (Author) , Wadepohl, Hubert (Author) , Enders, Markus (Author)
Format: Article (Journal)
Language:English
Published: 23 July 2018
In: Zeitschrift für anorganische und allgemeine Chemie
Year: 2018, Volume: 644, Issue: 14, Pages: 603
ISSN:1521-3749
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Author Notes:Helene Schall, Olaf Fritz, Margot Schikora, Jana Elias, Hans Pritzkow, Hubert Wadepohl, and Markus Enders
Description
Summary:The cover picture shows a new class of chiral phosphine ligands bearing three imidazole units bridged by boranes. The bowl shaped, C3 symmetric molecules are obtained by a simple condensation procedure. The steric bulk of these monodentate ligands can easily be adjusted over a large range by the use of different chiral or achiral boranes. The ligand character is determined by the almost pure s‐character of the phosphorous lone‐pair, leading to very short metal‐P distances. Details are discussed in the article by Markus Enders, Helene Schall, and Olaf Fritz, et al. on page 630 ff.
Item Description:Gesehen am 28.05.2019
Physical Description:Online Resource
ISSN:1521-3749

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