Sequentially rhodium-catalyzed enantioselective cycloisomerization-hydrogenation syntheses of alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes
Open image in new windowThe enantioselective Rh-catalyzed Alder-ene cycloisomerization of ester- and ether-tethered alkyne allyl alcohols is an excellent entry to subsequent Rh-catalyzed one-pot hydrogenations in the sense of sequentially Rh-catalyzed processes to chiral alkylidene butyrolactone β-h...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
24 May 2018
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| In: |
Chemistry of heterocyclic compounds
Year: 2018, Volume: 54, Issue: 3, Pages: 320-328 |
| ISSN: | 1573-8353 |
| DOI: | 10.1007/s10593-018-2267-1 |
| Online Access: | Verlag, Pay-per-use, Volltext: https://doi.org/10.1007/s10593-018-2267-1 |
| Author Notes: | Nadine Muschelknautz, Frank Rominger, Thomas J.J. Müller |
| Summary: | Open image in new windowThe enantioselective Rh-catalyzed Alder-ene cycloisomerization of ester- and ether-tethered alkyne allyl alcohols is an excellent entry to subsequent Rh-catalyzed one-pot hydrogenations in the sense of sequentially Rh-catalyzed processes to chiral alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes, respectively, with excellent levels of enantioselectivity. |
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| Item Description: | Gesehen am 14.06.2019 |
| Physical Description: | Online Resource |
| ISSN: | 1573-8353 |
| DOI: | 10.1007/s10593-018-2267-1 |