Sequentially rhodium-catalyzed enantioselective cycloisomerization-hydrogenation syntheses of alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes
Open image in new windowThe enantioselective Rh-catalyzed Alder-ene cycloisomerization of ester- and ether-tethered alkyne allyl alcohols is an excellent entry to subsequent Rh-catalyzed one-pot hydrogenations in the sense of sequentially Rh-catalyzed processes to chiral alkylidene butyrolactone β-h...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
24 May 2018
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| In: |
Chemistry of heterocyclic compounds
Year: 2018, Jahrgang: 54, Heft: 3, Pages: 320-328 |
| ISSN: | 1573-8353 |
| DOI: | 10.1007/s10593-018-2267-1 |
| Online-Zugang: | Verlag, Pay-per-use, Volltext: https://doi.org/10.1007/s10593-018-2267-1
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| Verfasserangaben: | Nadine Muschelknautz, Frank Rominger, Thomas J.J. Müller |
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| 245 | 1 | 0 | |a Sequentially rhodium-catalyzed enantioselective cycloisomerization-hydrogenation syntheses of alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes |c Nadine Muschelknautz, Frank Rominger, Thomas J.J. Müller |
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| 520 | |a Open image in new windowThe enantioselective Rh-catalyzed Alder-ene cycloisomerization of ester- and ether-tethered alkyne allyl alcohols is an excellent entry to subsequent Rh-catalyzed one-pot hydrogenations in the sense of sequentially Rh-catalyzed processes to chiral alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes, respectively, with excellent levels of enantioselectivity. | ||
| 650 | 4 | |a asymmetric catalysis | |
| 650 | 4 | |a cycloisomerization | |
| 650 | 4 | |a furanones | |
| 650 | 4 | |a homogeneous catalysis | |
| 650 | 4 | |a hydrogenation | |
| 650 | 4 | |a one-pot reactions | |
| 650 | 4 | |a rhodium | |
| 650 | 4 | |a sequential catalysis | |
| 650 | 4 | |a tetrahydrofurans | |
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