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Sequentially rhodium-catalyzed enantioselective cycloisomerization-hydrogenation syntheses of alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes

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Open image in new windowThe enantioselective Rh-catalyzed Alder-ene cycloisomerization of ester- and ether-tethered alkyne allyl alcohols is an excellent entry to subsequent Rh-catalyzed one-pot hydrogenations in the sense of sequentially Rh-catalyzed processes to chiral alkylidene butyrolactone β-h...

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Hauptverfasser: Muschelknautz, Nadine (VerfasserIn) , Rominger, Frank (VerfasserIn) , Müller, Thomas J. J. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 24 May 2018
In: Chemistry of heterocyclic compounds
Year: 2018, Jahrgang: 54, Heft: 3, Pages: 320-328
ISSN:1573-8353
DOI:10.1007/s10593-018-2267-1
Online-Zugang:Verlag, Pay-per-use, Volltext: https://doi.org/10.1007/s10593-018-2267-1
Volltext
Verfasserangaben:Nadine Muschelknautz, Frank Rominger, Thomas J.J. Müller
Beschreibung
Zusammenfassung:Open image in new windowThe enantioselective Rh-catalyzed Alder-ene cycloisomerization of ester- and ether-tethered alkyne allyl alcohols is an excellent entry to subsequent Rh-catalyzed one-pot hydrogenations in the sense of sequentially Rh-catalyzed processes to chiral alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethanes, respectively, with excellent levels of enantioselectivity.
Beschreibung:Gesehen am 14.06.2019
Beschreibung:Online Resource
ISSN:1573-8353
DOI:10.1007/s10593-018-2267-1

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